More than likely I would say.
Splits are similar up to the 2nd split, but then the last sector is about .5 seconds faster, which is impossible doing legally.
One last thing you can try before leaving it to the shop... download this program: http://viceroy25.tripod.com/regreswiz.zip
Use it to restore your registry files to a date just before the problems occurred. If you can log in then, immediately do our suggestions again like scanning with malwarebytes. Also try Trojan Remover.
Those entries I've quoted, you should delete.
I also see that you have both Avast and McAfee installed. Uninstall one of them, preferably McAfee since it's about 5 years old and pretty much useless now. It could be a conflict between the two of them that prevents them from loading properly, thus halting Windows.
Don't think about uploading to rapidshare. That would probably take days. Since your computer is 5 years old, I doubt it has a DVD burner, only regular CD burner. So for storing 10GB you would need about 15 discs. If you can boot into Safe Mode with networking, download Malwarebytes and run it. It would also be useful if you could download HijackThis and post an output from the log in generates. Then we can check for suspicious programs that runs on startup.
Shame on you Pearcy for not posting your problems on our forum! You know I could've fixed your problems easy, and got you set up with some decent protection, rather than that crappy McAfail and (No)Defender.